相转移催化合成乙酸苄酯的研究   总被引：4，自引：0，他引：4  

杨志成  张海峰 《华东地质学院学报》1996,19(1):73-78

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Nonequilibrium thermodynamics of pressure solution     

F. K. Lehner  J. Bataille 《Pure and Applied Geophysics》1984,122(1):53-85

This paper is concerned with the thermodynamic theory of solution and precipitation processes in wet crustal rocks and with the mechanism of steady pressure-solution slip in contact zones, such as grain-to-grain contacts, fracture surfaces, and permeable gouge layers, that are infiltrated by a mobile aqueous solution phase. A local dissipation jump condition at the phase boundary is fundamental to identifying the thermodynamic force driving the solution and precipitation process and is used here in setting up linear phenomenological relations to model near-equilibrium phase transformation kinetics. The local thermodynamic equilibrium of a stressed pure solid in contact with its melt or solution phase is governed by Gibbs's relation, which is rederived here, in a manner emphasizing its independence of constitutive assumptions for the solid while neglecting surface tension and diffusion in the solid. Fluid-infiltrated contact zones, such as those formed by rough surfaces, cannot generally be in thermodynamic equilibrium, especially during an ongoing process of pressure-solution slip, and the existing equilibrium formulations are incorrect in overlooking dissipative processes tending to eliminate fluctuations in superficial free energies due to stress concentrations near asperities, defects, or impurities. Steady pressure-solution slip is likely to exhibit a nonlinear dependence of slip rate on shear stress and effective normal stress, due to a dependence of the contact-zone state on the latter. Given that this dependence is negligible within some range, linear relations for pressure-solution slip can be derived for the limiting cases of diffusion-controlled and interface-reaction-controlled rates. A criterion for rate control by one of these mechanisms is set by the magnitude of the dimensionless quantityk/2C _pD, wherek is the interfacial transfer coefficient, is the mean diffusion path length,C _p is the solubility at pressurep, andD is the mass diffusivity.  相似文献   

相律的应用:蒸发结晶过程自由度          下载免费PDF全文

房春晖  宋彭生 《盐湖研究》1993,(1)

在连续原理和浓度限制条件的基础上,分析了卤水蒸发过程的自由度,提出了“蒸发结晶过程自由度”这一概念。发现蒸发结晶过程自由度在整个过程中不是1便是0,在1和0之间交替变化,与选择的组分数和析出固相数目无关。蒸发结晶过程自由度为1,物理意义是在不引起新相产生旧相不消失的前提下过程连续地变化(水分的连续蒸失),几何意义是指在适当的坐标系中的一条线,一条直线或曲线;0的物理意义是指新相的产生和旧相的即将消失或者前一段的连续变化过渡到后一段的连续变化,几何意义是指一点,两蒸发阶段的交点或者过程的终点。简单地讨论了过程的单向性和连续件。  相似文献   

东台吉乃尔盐湖卤水的相化学研究（Ⅱ）—冬夏季卤水蒸发实验   总被引：1，自引：0，他引：1       下载免费PDF全文

张宝全  刘铸唐 《盐湖研究》1994,2(3):27-34

为了研究东台吉乃尔盐湖卤水蒸发时的相化学，确定钾、镁和锂盐的结晶特性，在实验室内２５℃等温蒸发实验基础上和自然条件下进行了冬夏季日晒蒸发试验．东台吉乃尔盐湖卤水是由氯化钠饱和的多组分复杂体系构成的．卤水中存在的离子是Ｎａ＋、Ｋ＋、Ｍｇ２＋、Ｌｉ＋、Ｃａ２＋、Ｂ３＋、ＳＯ４２－和Ｃｌ－．试验数据与Ｎａ＋、Ｋ＋、Ｍｇ２＋Ｃｌ－、ＳＯ４２－ＫＨ２Ｏ五元体系介稳平衡数据进行了讨论和比较．Ａｕｔｅｎｒｉｅｔｈ相图被用来表示各数据间的关系和证明冬夏季蒸发时结晶行为的差别．  相似文献   

Application of AMD to the Determination of Cropprotection Agents in Drinking Water. Part III: Solid Phase Extraction and Affecting Factors Anwendung der AMD-Technik zur Bestimmung von Pflanzenbehandlungsmittel-Wirkstoffen im Trinkwasser. Teil III: Festphasenextraktion und ihre Einflußfaktoren     

G. Pfaab  H. Jork 《洁净——土壤、空气、水》1994,22(5):216-223

The more sensitive an analysis method the more care must be given to sample preparation. Solid phase extraction (SPE) onto RP 18 phases has established itself as a general purification and enrichment technique for trace components in aqueous samples. Various factors may thereby influence the recovery rate. For example, the ratio amount of sorbent and sample volume should be taken into account to avoid breakthrough of the investigated substance. Extracting phenylurea herbicides from drinking water, the ratio should be 1 g RP 18 sorbent per 1 L water sample. Concerning the flow rate for the fungicides procymidone, vinclozolin, and iprodione, the recovery rate decreases using higher flow rates than 3 or 6 mL/min. In the case of phenylurea herbicides, a flow rate of 10 or 14 mL/min showed best results. Even the coefficient of variation is below ± 5% at these flow rates. Furthermore, the company dependence should be considered because the recovery rate might differ by up to 40% using the nominally identical material. The same applies to the batch dependence of quality from the same company. The concentration of the eluate must also be monitored and carried out with great care to avoid decreasing the recovery rate. Considering these factors of influence, SPE is a very useful tool in sample preparation, particularly if an automated system is used.  相似文献   

氧化镍、二氧化钛高压相变及电导率压力效应   总被引：1，自引：0，他引：1       下载免费PDF全文

熊大和  刘顺 《地球物理学报》1994,37(1):120-123

采用金刚石对顶砧压腔静高压技术，对氧化镍、二氧化钛在０-３２ＧＰａ压力范围内的电导率进行了测量．结果表明，电导率－压力关系曲线上的一些特征点与同一物质的高压相交点具有一致性．  相似文献   

Stochastic assessment of GPS carrier phase measurements for precise static relative positioning   总被引：17，自引：11，他引：17  

J. Wang  C. Satirapod  C. Rizos 《Journal of Geodesy》2002,76(2):95-104

 Global positioning system (GPS) carrier phase measurements are used in all precise static relative positioning applications. The GPS carrier phase measurements are generally processed using the least-squares method, for which both functional and stochastic models need to be carefully defined. Whilst the functional model for precise GPS positioning is well documented in the literature, realistic stochastic modelling for the GPS carrier phase measurements is still both a controversial topic and a difficult task to accomplish in practice. The common practice of assuming that the raw GPS measurements are statistically independent in space and time, and have the same accuracy, is certainly not realistic. Any mis-specification in the stochastic model will inevitably lead to unreliable positioning results. A stochastic assessment procedure has been developed to take into account the heteroscedastic, space- and time-correlated error structure of the GPS measurements. Test results indicate that the reliability of the estimated positioning results is improved by applying the developed stochastic assessment procedure. In addition, the quality of ambiguity resolution can be more realistically evaluated. Received: 13 February 2001 / Accepted: 3 September 2001  相似文献   

精密引潮位展开及某些诠释   总被引：8，自引：2，他引：8       下载免费PDF全文

郗钦文 《地球物理学报》1991,34(2):182-194

作者再次改进了引潮位展开,潮波振幅给到小数后第六位,共3070个潮波.文中论述了引潮位展开的精度,同时给出为了保证潮汐计算的高精度而所需引入的各项改正及其说明.  相似文献   

地球内部物质组成及其性质的研究     

臧绍先  宁杰远 《地球物理学进展》1993,(2)

地球内部物质组成的研究涉及对地表现象的深入解释,与地球动力学、地球热结构及宇宙演化有着密切的关系.本文综述了这方面的研究结果及近期的进展,指出两种地幔模型的主要分歧点,讨论了地幔中的主要相变及与间断面的关系,对今后研究提出四点意见.  相似文献   

冷迳流的稳定性及其解析解的分析     

欧阳首承  朱克云  肖天贵 《大气科学》1992,16(4):502-507

本文利用相法讨论了y方向无限伸延的冷迳流方程.首先发现其非线性项作用由于z方向上的补偿作用而消失,即其相空间的方程是四阶线性常微分方程.利用Hurwitz方法分析其稳定时,证明了唯有中性大气符合冷迳流的稳定性条件.其解析解的趋势表明与观测结果类似.  相似文献